Oxidative stability of fatty acid alkyl esters: a review.


  • Michal Angelovič Slovak University of Agriculture in Nitra, Faculty of Engineering, Department of Transport and Handling, Tr. A. Hlinku 2, 949 76 Nitra
  • Juraj Jablonický Slovak University of Agriculture in Nitra, Faculty of Engineering, Department of Transport and Handling, Tr. A. Hlinku 2, 949 76 Nitra
  • Zdenko Tkáč Slovak University of Agriculture in Nitra, Faculty of Engineering, Department of Transport and Handling, Tr. A. Hlinku 2, 949 76 Nitra
  • Marek Angelovič Slovak University of Agriculture in Nitra, Faculty of Engineering, Department of Machines and Production Systems, Tr. A. Hlinku 2, 949 76 Nitra




biodiesel, vegetable oil, fatty acid, oxidation, stability


The purpose of this study was to investigate and to process the current literary knowledge of the physico-chemical properties of vegetable oil raw used for biodiesel production in terms of its qualitative stability. An object of investigation was oxidative stability of biodiesel. In the study, we focused on the qualitative physico-chemical properties of vegetable oils used for biodiesel production, oxidative degradation and its mechanisms, oxidation of lipids, mechanisms of autooxidation, effectivennes of different synthetic antioxidants in relation to oxidative stability of biodiesel and methods of oxidative stability determination. Knowledge of the physical and chemical properties of vegetable oil as raw material and the factors affecting these properties is critical for the production of quality biodiesel and its sustainability. According to the source of oilseed, variations in the chemical composition of the vegetable oil are expressed by variations in the molar ratio among different fatty acids in the structure. The relative ratio of fatty acids present in the raw material is kept relatively constant after the transesterification reaction. The quality of biodiesel physico-chemical properties is influenced by the chain length and the level of unsaturation of the produced fatty acid alkyl esters. A biodiesel is thermodynamically stable. Its instability primarily occurs from contact of oxygen present in the ambient air that is referred to as oxidative instability. For biodiesel is oxidation stability a general term. It is necessary to distinguish ‘storage stability' and ‘thermal stability', in relation to oxidative degradation, which may occur during extended periods of storage, transportation and end use. Fuel instability problems can be of two related types, short-term oxidative instability and long-term storage instability. Storage instability is defined in terms of solid formation, which can plug nozzles, filters, and degrade engine performance. Biodiesels are more susceptible to degradation compared to fossil diesel because of the presence of unsaturated fatty acid chain in it. The mechanisms of oxidative degradation are autoxidation in presence of atmospheric oxygen; thermal or thermal-oxidative degradation from excess heat; hydrolysis in presence of moisture or water during storage and in fuel lines; and microbial contamination from contact with dust particles or water droplets containing fungi or bacteria into the fuel. The oxidation of lipids is a complex process in which unsaturated fatty acids are reacted with molecular oxygen by means of free radicals. The radicals react with lipids, and cause oxidative destruction of unsaturated, polyunsaturated fatty acids, therefore, known as lipid peroxidation. The factors such as heat, oxygen, light, and some metal ions, especially iron and copper, also play a significant role in creating oxidation. Oxidative products formed in biodiesel affect fuel storage life, contribute to deposit formation in tanks, and they may cause clogging of fuel filters and injection systems. The volatile organic acids formed as secondary by products of the oxidative degradation, may stimulate corrosion in the fuel system. Poor stability can lead to increasing acid numbers, increasing fuel viscosity, and the formation of gums and sediments. In general, antioxidants can prevent oxidation. Biodiesel, because it contains large numbers of molecules with double bonds, is much less oxidatively stable than petroleum-based diesel fuel. Oxidation stability is the important parameter to determine the storage of biodiesel for longer period of time. Biodiesel samples were evaluated according to methods on the base of kept in contact with pure oxygen at elevated temperatures and pressures. The results show that the performance antioxidants variation is observed for biodiesel. The most commonly used primary synthetic antioxidants


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Abreu, F. R., Lima, D. G., Hamú, C. W., Suarez, P. A. Z. 2004. Utilization of metal complexes as catalysts in the transesterification of Brazilian vegetable oils with different alcohols. Journal of Molecular Catalysis A: Chemical, vol. 209, p. 29-33. https://doi.org/10.1016/j.molcata.2003.08.003 DOI: https://doi.org/10.1016/j.molcata.2003.08.003

American Oil Chemists Society - AOCS. 1997. Official and tentative methods. 3. ed. Chicago : AOCS, vol. 1.

Araújo, S. V., Murilo, F., Luna, T., Rola, E. M., Azevedo, D. C. S., Cavalcante, C. L. 2009. A rapid method for evaluation of the oxidation stability of castor oil FAME: influence of antioxidant type and concentration. Fuel Processing Technology, vol. 90, p. 1272-1277. https://doi.org/10.1016/j.fuproc.2009.06.009 DOI: https://doi.org/10.1016/j.fuproc.2009.06.009

Angelovič, M., Tkáč, Z., Angelovič, M. 2013. Oilseed rape as feedstock for biodiesel production in Relation to the environment and human health. Potravinarstvo, vol. 7, no. 1, p. 101-106. https://doi.org/10.5219/278 DOI: https://doi.org/10.5219/278

Atabani, A. E., Silitonga, A. S., Ong, H. C., Mahlia, T. M. I., Masjuki, H. H., Badruddin, I. A., et al. 2013. Non-edible vegetable oils: a critical evaluation of oil extraction, fatty acid compositions, biodiesel production, characteristics, engine performance and emissions production. Renewable Sustainable Energy Reviews, vol. 18, p. 211-245. https://doi.org/10.1016/j.rser.2012.10.013 DOI: https://doi.org/10.1016/j.rser.2012.10.013

Atadashi, I. M., Aroua, M. K., Abdul Aziz, A. R., Sulaiman, N. M. N. 2012. Production of biodiesel using high free fatty acid feedstocks. Renewable Sustainable Energy Reviews, vol. 16, no. 5, p. 3275-3285. https://doi.org/10.1016/j.rser.2012.02.063 DOI: https://doi.org/10.1016/j.rser.2012.02.063

Ball, J., Shah, R., Mahajan, D., Patel, S., Colantuoni, V., Maraj, R. 2009. Oxidation stability in biodiesel: a brief review of current technology. [cit. 2015-06-02]. Available at: http://www.biodiesel-magazine.com/article- print.jsp?article_id=35 41. (accessed 2010-02-02)

Berman, P., Nizri, S., Wiesman W. 2011. Castor oil biodiesel and its blends as alternative fuel. Biomass and Bioenergy, vol. 35, p. 2861-2866. https://doi.org/10.1016/j.biombioe.2011.03.024 DOI: https://doi.org/10.1016/j.biombioe.2011.03.024

Bergström S. 1945. Autoxidation of linoleic acid. Nature, vol. 156, p. 717-718. DOI: https://doi.org/10.1038/156717b0

Bergström, S., Blomstrand, R., Laurell, S. 1950. On the autoxidation of linoleic acidin aqueous colloidal solution. Acta Chemica Scandinavica, vol. 4, p. 245-250. https://doi.org/10.3891/acta.chem.scand.04-0245 DOI: https://doi.org/10.3891/acta.chem.scand.04-0245

Biodiesel 2020: A Global Market Survey, 2008. 2nd ed. Houston, TX USA : Emerging Markets Online, (EMO). 685 p. [cit. 2015-06-02]. Available at: http://www.emerging-markets.com/biodiesel/

Bolland, J. 1949. Kinetics of olefin oxidation. Quarterly Review of the Chemical Society, vol. 3, 1949, p. 1-21. DOI: https://doi.org/10.1039/qr9490300001

Borugadda, V. B., Goud, V. V. 2012. Biodiesel production from renewable feedstocks: status and opportunities. Renewable and Sustainable Energy Reviews, vol. 16, p. 4763-4784. https://doi.org/10.1016/j.rser.2012.04.010 DOI: https://doi.org/10.1016/j.rser.2012.04.010

Bouaid, A., Martinez, M., Aracil, J. 2007. Long storage stability of biodiesel from vegetable and used frying oils. Fuel, vol. 86, no. 16, p. 2596-2602. https://doi.org/10.1016/j.fuel.2007.02.014 DOI: https://doi.org/10.1016/j.fuel.2007.02.014

Choe, E., Min, D. B. 2006. Mechanisms and factors of edible oil oxidation. Comprehensive Reviews in Food Science and Safety, vol. 5, p. 169-186. https://doi.org/10.1111/j.1541-4337.2006.00009.x DOI: https://doi.org/10.1111/j.1541-4337.2006.00009.x

Costa Neto, P. R., Rossi, L. F. S., Zagonel, G. F., Ramos, L. P. 2000. Produção de biocombustível alternativo ao óleo diesel através da transesterificação de óleo de soja usado em frituras. Química Nova, vol. 23, p. 531-537. https://doi.org/10.1590/S0100-40422000000400017 DOI: https://doi.org/10.1590/S0100-40422000000400017

Dubey, N. K. 2015. Plants as a Source of Natural Antioxidants, 1st ed. CABI. 320 p. ISBN-13: 978178064-266-6. https://doi.org/10.1079/9781780642666.0000 DOI: https://doi.org/10.1079/9781780642666.0000

Dunn, R. O. 2000. Analysis of oxidative stability of methyl soyate by pressurized-differential scanning calorimetry. Transactions of the American Society of Agricultural Engineers, vol. 43, no. 5, p. 1203-1208. https://doi.org/10.13031/2013.3013 DOI: https://doi.org/10.13031/2013.3013

Dunn, R. O. 2002. Effect of oxidation under accelerated conditions on fuel properties of methyl soyate (biodiesel). Journal of the American Chemical Society, vol. 79, no. 9, p. 915-920. https://doi.org/10.1007/s11746-002-0579-2 DOI: https://doi.org/10.1007/s11746-002-0579-2

Dunn, R. O. 2005a. Oxidative stability of soybean oil fatty acid methyl esters by oil stability index (OSI). Journal of the American Oil Chemists' Society, vol. 82, no. 5, p. 381-387. https://doi.org/10.1007/s11746-005-1081-6 DOI: https://doi.org/10.1007/s11746-005-1081-6

Dunn, R. O. 2005b. Effect of antioxidants on the oxidative stability of methyl soyate (biodiesel). Fuel Processing Technolog, vol. 86, no. 10, p. 1071-1085. https://doi.org/10.1016/j.fuproc.2004.11.003 DOI: https://doi.org/10.1016/j.fuproc.2004.11.003

Dunn, R. O. 2006. Oxidative stability of biodiesel by dynamic mode pressurized-differential scanning calorimetry (P-DSC). Transactions of the American Society of Agricultural Engineers, vol. 49, p. 1633-1641. [cit. 2015-06-02]. Available at: http://biodiesel.org/reports/20000701_gen376.pdf DOI: https://doi.org/10.13031/2013.22022

Dunn, R. O. 2008a. Antioxidants for improving storage stability of biodiesel. Biofuels, Bioproducts and Biorefining, vol. 2, p. 304-318. https://doi.org/10.1002%2fbbb.83 DOI: https://doi.org/10.1002/bbb.83

Dunn, R. O. 2008b. Effect of temperature on the oil stability index of biodiesel. Energy Fuels, vol. 22, no. 1, p. 657-662. https://doi.org/10.1021/ef700412c DOI: https://doi.org/10.1021/ef700412c

Dwivedi, G., Sharma, M. P. 2014a. Prospects of biodiesel from Pongamia in India. Renewable and Sustainable Energy Reviews, vol. 32, p. 114-122. https://doi.org/10.1016/j.rser.2014.01.009 DOI: https://doi.org/10.1016/j.rser.2014.01.009

Dwivedi, G., Sharma, M. P. 2014b. Impact of Antioxidant and Metals on Biodiesel Stability: A Review. Journal of Materials and Environmental Science, vol. 5, no. 5, p. 1412-1425. [cit. 2015-06-02]. Available at: http://www.jmaterenvironsci.com/Document/vol5/vol5_N5/174-JMES-1000-2014%20Dwivedi.pdf

EN 14214 Automotive fuels. Fatty acid methyl esters (FAME) for diesel engines. Requirements and test methods.

Encinar, J. M., Gonzáles, J. F., Rodríguez, J. J., Tejedor, A. 2002. Biodiesel fuels from vegetables Oils: Transesterification of Cynara cardunculus L. oils with ethanol. Energy & Fuels, vol. 19, p. 443-450. https://doi.org/10.1021/ef010174h DOI: https://doi.org/10.1021/ef010174h

Encinar, J. M., González, J. F., Pardal, A. Martínez, G. 2010. Transesterification of rapeseed oil with methanol in the presence of various co-solvents. The third International Symposium on Energy from Biomass and Waste [online] Vence : CISA, Environmental Sanitary Engineering Centre, Italy. [cit. 2015-06-02]. Available at: http://comum.rcaap.pt/bitstream/123456789/1297/1/Transesterification%20of%20rapeseed%20oil%20with%20methanol%20in%20the%20presence%20of%20various%20cosolvents. pdf

Ferrari, R. A., Oliveira, V. S., Scabio, A. 2005. Oxidative stability of biodiesel from soybean oil fatty acid ethyl esters. Scientia Agricola (Piracicaba, Braz.), vol. 62, no.3, p. 291-295. https://doi.org/10.1590/S0103-90162005000300014 DOI: https://doi.org/10.1590/S0103-90162005000300014

Focke, W. W., Westhuizen, I. V. D., Grobler, A. B. L., Nshoane, K. T., Reddy, J. K., Luyt, A. S. 2012. The effect of synthetic antioxidants on the oxidative stability of biodiesel. Fuel, vol. 94, p. 227-233. https://doi.org/10.1016/j.fuel.2011.11.061 DOI: https://doi.org/10.1016/j.fuel.2011.11.061

Formo, M. W., Jungermann, E., Noris, F., Sonntag, N. O. V. 1979. Bailey's Indust Oil Fat Products. John Wiley and Son, vol. 1, no. 4, p. 698-711.

Frankel, E. N. 1993. In search of better methods to evaluate natural antioxidants and oxidative stability in food lipids. Trends in Food Science and Technology, vol. 4, p. 220-225. https://doi.org/10.1016/0924-2244(93)90155-4 DOI: https://doi.org/10.1016/0924-2244(93)90155-4

Graboski, M. S., McCormick, R. L. 1998. Combustion of fat and vegetable oil derived fuels in diesel engines. Progress in Energy and Combustion Science, vol. 24, p. 125-164. https://doi.org/10.1016/S0360-1285(97)00034-8 DOI: https://doi.org/10.1016/S0360-1285(97)00034-8

Gray, J. I. 1978. Measurement of lipid oxidation: A review. Journal of the American Oil Chemists' Society, vol. 55, p. 539-546. https://doi.org/10.1007/bf02668066 DOI: https://doi.org/10.1007/BF02668066

Gui, M. M., Lee, K. T., Bhatia, S. 2008. Feasibility of edible oil vs. non-edible oil vs. waste edible oil as biodiesel feedstock. Energy, vol. 33, no. 11, p. 1646-1653. https://doi.org/10.1016/j.energy.2008.06.002 DOI: https://doi.org/10.1016/j.energy.2008.06.002

Gunstone, F. D. 2001. Basic oleochemicals, oleochemical products and new industrial oils. In Gunstone, F. D., Hamilton, R. J. Oleochemical Manufacture and Applications. Sheffield : Academic, 2001, p. 1-22.

Gunstone, F. D. 2008. Disappearance. Lipid Technology [online], vol. 20, no. 2, p. 48 [cit. 2015-07-15]. ISSN: 1863-5377. DOI: https://doi.org/10.1002/lite.200800007

Gunstone, F. D. 2009. Non-food uses of vegetable oils. Lipid Technology, vol. 21, no. 7, p. 164. https://doi.org/10.1002/lite.200900039 DOI: https://doi.org/10.1002/lite.200900039

Haas, M. J., Scott, K. M., Alleman, T. L., Mccormick, R. L. 2001. Engine performance of biodiesel fuel prepared from soybean soapstock: a high quality renewable fuel produced from a waste feedstock. Energy & Fuels, vol. 15, p. 1207-1212. https://doi.org/10.1021/ef010051x DOI: https://doi.org/10.1021/ef010051x

Hoshino, T., Iwata, I., Koseki, H. 2007. Oxidation stability and risk evaluation of biodiesel. Thermal Science, vol. 11, p. 87-100. https://doi.org/10.2298/TSCI0702087H DOI: https://doi.org/10.2298/TSCI0702087H

Imahara, H., Minami, E., Hari, S., Saka, S. 2008. Thermal stability of biodiesel in supercritical methanol. Fuel, vol. 87, p. 1-6. https://doi.org/10.1016/j.fuel.2007.04.003 DOI: https://doi.org/10.1016/j.fuel.2007.04.003

Ingold, K. 1961. Inhibition of the autoxidation of organic substances in the liquid phase. Chemical Reviews, vol. 61, p. 563-589. DOI: https://doi.org/10.1021/cr60214a002

Jain, S., Sharma, M. P. 2010. Stability of biodiesel and its blends: a review. Renewable & Sustainable Energy Reviews, vol. 14, p. 667-678. https://doi.org/10.1016/j.rser.2009.10.011 DOI: https://doi.org/10.1016/j.rser.2009.10.011

Jain, S., Sharma, M. P. 2011. Study of oxidation stability of Jatropha curcas biodiesel/diesel blends. International Journal of Energy and Environment, vol. 2, no. 3, p. 533-542.

Jain, S., Sharma, M. P. 2013. Effect of metal contaminants and antioxidants on the storage stability of Jatropha curcas biodiesel. Fuel, vol. 109, p. 379-383. https://doi.org/10.1016/j.fuel.2013.03.050 DOI: https://doi.org/10.1016/j.fuel.2013.03.050

Kanner, J., Rosenthal, I. 1992. An Assessment of lipid oxidation in foods. Pure and Applied Chemistry, vol. 64, no. 12, p. 1959-1964. https://doi.org/10.1351/pac199264121959 DOI: https://doi.org/10.1351/pac199264121959

Karavalakis, G., Hilari, D., Givalou, L., Karonis, D., Stournas, S. 2011. Storage stability and ageing effect of biodiesel blends treated with different antioxidants. Energy, vol. 36, no. 1, p. 369-374. https://doi.org/10.1016/j.energy.2010.10.029 DOI: https://doi.org/10.1016/j.energy.2010.10.029

Kemin Industries Inc, 2010. [online] [cit. 2015-06-03]. Available at: http://foodquality.wfp.org/FoodSpecifications/Shelflifeoffoods/Oxidation/tabid/472/Default.aspx?PageContentMode=1

Knothe, G., Dunn, R. O. 2003a. Oxidative stability of biodiesel in blends with jet fuel by analysis of oil stability index. Journal of the American Oil Chemists' Society, vol. 80, no. 10, p. 1047-1048. https://doi.org/10.1007/s11746-003-0818-6 DOI: https://doi.org/10.1007/s11746-003-0818-6

Knothe, G., Dunn, R. 2003b. Dependence of oil stability index of fatty compounds on their structure and concentration and presence of metals. Journal of the American Oil Chemists' Society, vol. 80, no. 10, p. 1021-1026. https://doi.org/10.1007/s11746-003-0814-x

Knothe, G. H., Dunn, R. O. 2003c. Influence of compound structure, concentration and presence of metals on oxidative stability of fatty compounds by the oil stability index method. Journal of the American Oil Chemists' Society, vol. 80, no. 10, p. 1021-1026. DOI: https://doi.org/10.1007/s11746-003-0814-x

Knothe, G. 2005. Dependence of biodiesel fuel properties on the structure of fatty acid alkyl esters. Fuel Processing Technology, vol. 86, no. 10, p. 1059-1070. https://doi.org/10.1016/j.fuproc.2004.11.002 DOI: https://doi.org/10.1016/j.fuproc.2004.11.002

Knothe, G. 2007. Some aspects of biodiesel oxidative stability. Fuel Processing Technology, vol. 88, p. 669-677. https://doi.org/10.1016/j.fuproc.2007.01.005 DOI: https://doi.org/10.1016/j.fuproc.2007.01.005

Knothe, K. 2008. ''Designer'' Biodiesel: optimizing fatty ester composition to improve fuel properties. Energy Fuels, vol. 22, no. 2, p. 1358-1364. https://doi.org/10.1021/ef700639e DOI: https://doi.org/10.1021/ef700639e

Litwinienko, G., Daniluk, A., Kasprzycka-Guttman, T. 2000. Study on autoxidation kinetics of fats by differential scanning calorimetry. 1. Saturated C12-C18 fatty acids and their esters. Industrial and Engineering Chemistry Research, vol. 39, no. p. 7-12. DOI: https://doi.org/10.1021/ie9905512

Litwinienko, G., Kasprzycka-Guttman, T. 2000. Study on autoxidation kinetics of fat components by differential scanning calorimetry. 2. Unsaturated fatty acids and their esters. Industrial and Engineering Chemistry Research, vol. 39, p. 13-17. https://doi.org/10.1021/ie990552u DOI: https://doi.org/10.1021/ie990552u

Litwinienko, G. 2001. Autoxidation of unsaturated fatty acids and their esters. Journal of Thermal Analysis and Calorimetry, vol. 65, no. 2, p. 639-646. https://doi.org/10.1023/A:1017974313294 DOI: https://doi.org/10.1023/A:1017974313294

Manura, J. J. 1994. Detection and Identification of Volatile and Semi-Volatile Organics In Synthetic Polymers Used In Food and Pharmaceutical Packaging. ASMS Meeting. Chicago, IL.

Marchetti, J. M., Miguel, V. U., Errazu, A. F. 2007. Possible methods for biodiesel production. Renewable Sustainable Energy Reviews, vol. 11, p. 1300-1311. https://doi.org/10.1016/j.rser.2005.08.006 DOI: https://doi.org/10.1016/j.rser.2005.08.006

McCormick, R. L., Ratcliff, M., Moens, L., Lawrence, R. 2007. Several factors affecting the stability of biodiesel in standard accelerated test. Fuel Processing Technology, vol. 88, p. 651-657. https://doi.org/10.1016/j.fuproc.2007.01.006 DOI: https://doi.org/10.1016/j.fuproc.2007.01.006

Min, D. B, Bradley, G. D. 1992. Fats and oils: flavors. IN: Hui, Y. H. Wiley encyclopedia of food science and technology. New YORK : John Wiley and Sons, p. 828-832.

Monyem, A., Van Gerpen, J. H., Canakci, M. 2001. The effect of timing and oxidation emissions from biodiesel-fueled engines. Transactions of the ASAE, vol. 44, p. 35-42. https://doi.org/10.13031/2013.2301 DOI: https://doi.org/10.13031/2013.2301

Motasemi, F., Ani, F. N. 2012. A review on microwave-assisted production of biodiesel. Renewable Sustainable Energy Reviews, vol. 16, p. 4719-4733. https://doi.org/10.1016/j.rser.2012.03.069 DOI: https://doi.org/10.1016/j.rser.2012.03.069

Mushrush, G. W., Beal, E. J., Hughes, J. M., Wynne, J. H., Sakran, J. V., Hardy, D. R. 2000. Biodiesel fuels: use of soy oil as a blending stock for middle distillate petroleum fuels. Industry and Engineering Chemistry Resource, vol. 39, p. 3945-3948. https://doi.org/10.1021/ie0003640 DOI: https://doi.org/10.1021/ie0003640

Mushrush, G. W., Mose, D. G., Wray, C. L., Sullivan, K. T. 2001. Biofuels as a means of improving the quality of petroleum middle distillate fuels. Energy Sources, vol. 23, p. 649-655. https://doi.org/10.1080/00908310152004746 DOI: https://doi.org/10.1080/00908310152004746

Natarajan, E. 2012. Stability Studies of Biodiesel. International Journal of Energy Science, vol. 2, no. 4, p.152-155.

Noureddini, H., Harkey, D., Medikonduru, V. A. 1998. Continuous process for the conversion of vegetable oil into methyl esters of fatty acids. Journal of the AOCS, vol. 75, p. 1775-1783. https://doi.org/10.1007/s11746-998-0331-1 DOI: https://doi.org/10.1007/s11746-998-0331-1

Obadiah, A., Kannan, R., Ramasubbu, A., Kumar, S. V. 2012. Studies on the effect of antioxidants on the long-term storage and oxidation stability of Pongamia pinnata (L.) Pierre biodiesel. Fuel Processing Technology, vol. 99, p. 56-63. https://doi.org/10.1016/j.fuproc.2012.01.032 DOI: https://doi.org/10.1016/j.fuproc.2012.01.032

Ong, H. C., Silitonga, A. S. Masjuki, H. H., Mahlia, T. M. I., Chong, W. T., Boosroh, M. H. 2013. Production and comparative fuel properties of biodiesel from non-edible oils: Jatropha curcas, Sterculia foetida and Ceiba pentandra. Energy Convers Manage, vol. 73, p. 245-255. https://doi.org/10.1016/j.enconman.2013.04.011 DOI: https://doi.org/10.1016/j.enconman.2013.04.011

Ozturk, S., Cakmakcib, S. 2006. The effect of antioxidants on butter in relation to storage temperature and durative. The European Journal of Lipid Science and Technology, vol. 108, p. 951-959. https://doi.org/10.1002/ejlt.200600089 DOI: https://doi.org/10.1002/ejlt.200600089

Pacheco, M. T. B. 1991. Obtenção e fracionamento do óleo do fígado de tubarão azul (Prionace glauca) e sua estabilização com antioxidantes. Campinas: UNICAMP. 123 p. (Dissertação - Mestrado).

Peter Cremer North America, Lp. Phytosterol esters. Patent owner: Blagdon, P. North America. Patent No. US 20070031571 A1. 2007-02-08.

Pospisil, J., Klemchuk, P. P. 1990. Oxidation inhibition in organic materials. Boca Raton, F. L. : CRC Press Inc. p. 1.

Prankl, H., Schindlbauer, H. 1998. Oxidation stability of fatty acid methyl esters. In 10th European conference on biomass for energy and industry. Würzburg, Germany.

Pullen, J, Saeed, K. 2012. An overview of biodiesel oxidation stability. Renewable Sustainable Energy Reviews, vol. 16, no. 8, p. 5924-5950. https://doi.org/10.1016/j.rser.2012.06.024 DOI: https://doi.org/10.1016/j.rser.2012.06.024

Refaat, A. A. 2010. Different techniques for the production of biodiesel from waste vegetable oil. International Journal of Environmental Science and Technology, vol. 7, no. 1, p. 183-213. https://doi.org/10.1007/BF03326130 DOI: https://doi.org/10.1007/BF03326130

Sakac, V., Sakac, M. 2000. Free oxygen radiacals and kidney diseases - part I. Medicinski pregled, vol. 53, no. 9-10, p. 463-744.

Salehpour, S, Dube, M. A. 2008. The use of biodiesel as a green polymerization solvent at elevated temperatures. Polymer International, vol. 57, no. 6, p. 854-862. https://doi.org/10.1002/pi.2413 DOI: https://doi.org/10.1002/pi.2413

Salehpour, S., Dube, M. A., Murphy, M. 2009. Solution polymerization of styrene using biodiesel as a solvent: Effect of biodiesel feedstock. The Canadian Journal of Chemical Engineering, vol. 87, no. 1, p. 129-135. https://doi.org/10.1002/cjce.20085 DOI: https://doi.org/10.1002/cjce.20085

Sanjid, A., Masjuki, H. H., Kalam, M. A., Rahman, S. M. A., Abedin, M. J., Palash, S. M. 2013. Impact of palm, mustard, waste cooking oil and Calophyllum inophyllum biofuels on performance and emission of CI engine. Renewable Sustainable Energy Reviews, vol. 27, p. 664-682. https://doi.org/10.1016/j.rser.2013.07.059 DOI: https://doi.org/10.1016/j.rser.2013.07.059

Santos, N. A., Tavares, M. L. A., Rosenhaim, R., Silva, F. C., Fernandes, Jr. V. J., Santos, I. M. G., et al. 2007. Themogravimetric and calorimetric evaluation of babassu biodiesel obtained by the methanol route. Journal of Thermal Analysis and Calorimetry, vol. 87, p. 649-652. https://doi.org/10.1007/s10973-006-7765-1 DOI: https://doi.org/10.1007/s10973-006-7765-1

Schober, S., Mittelbach, M. 2004. The impact of antioxidants on biodiesel oxidation stability. European Journal of Lipid Science and Technology, vol. 106, p. 382-389. https://doi.org/10.1002/ejlt.200400954 DOI: https://doi.org/10.1002/ejlt.200400954

Schuchardt, U., Sercheli, R., Vargas, R. M. 1998. Transesterification of vegetable oils: a review. Journal of the Brazilian Chemical Society, vol. 9, p. 199-210. https://doi.org/10.1590/S0103-50531998000300002 DOI: https://doi.org/10.1590/S0103-50531998000300002

Shahidi, F., Zhong, Y. 2005. Antioxidants: Regulatory Status. Bailey's Industrial Oil and Fat Products. Canada : Memorial University of Newfoundland. p. 491-512. https://doi.org/10.1002/047167849X.bio035 DOI: https://doi.org/10.1002/047167849X.bio035

Silitonga, A. S., Ong, H. C., Mahlia, T. M. I., Masjuki, H. H., Chong, W. T. 2013. Characterization and production of Ceiba pentandra biodiesel and its blends. Fuel, vol. 108, p. 855-858. https://doi.org/10.1016/j.fuel.2013.02.014 DOI: https://doi.org/10.1016/j.fuel.2013.02.014

Tkáčová, J., Angelovičová, M., Haščík, P., Bobko, M. 2015. Oxidative stability of chicken meat during storage influenced by the feeding of alfalfa meal Potravinarstvo, vol. 9, no. 1, p. 106-111. https://doi.org/10.5219/444 DOI: https://doi.org/10.5219/444

Van Gerpen, J., Shanks, B., Pruszko, R., Clements, D., Knothe, G. 2004. Biodiesel Production Technology, August 2002-January 2004: subcontractor report. Colorado: National Renewable Energy Laboratory. 105 p. DOI: https://doi.org/10.2172/15008801

Wąsowicz, E., Gramza, A., Hęoe, M., Jeleń, H., H., Korczak, J., Małecka, M., Mildner-Szkudlarz, S., Rudzińska, M., Samotyja, U., Zawirska-Wojtasiak, R. 2004. Oxidation of lipids in food. Polish Journal of Food and Nutrition Sciences, vol. 13/54, SI 1, p. 87-100.

Yaakob, Z., Mohammad, M., Alherbawi, M., Alam, Z., Sopian, K. 2013. Overview of the production of biodiesel from Waste cooking oil. Renewable Sustainable Energy Reviews, vol. 18, p. 184-193. https://doi.org/10.1016/j.rser.2012.10.016 DOI: https://doi.org/10.1016/j.rser.2012.10.016




How to Cite

Angelovič, M. ., Jablonický, J. ., Tkáč, Z. ., & Angelovič, M. . (2015). Oxidative stability of fatty acid alkyl esters: a review. Potravinarstvo Slovak Journal of Food Sciences, 9(1), 417–426. https://doi.org/10.5219/500

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